First time ripping sprites, need a little advice

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Opening the game up in Tinke doesn't seem to bring anything readable, so the other option would be to manually rip them via DeSmuME.

Bleach: Dark Souls is a bit of an unusual case for DeSmuME, where you can't really remove any of the backgrounds without having the character sprites gone as well.

Therefore, the only option would be to play through the game and either use printscreen to capture the sprites (and manually remove the backgrounds, or use a frame capturing program such as animget to play through the game and sort through the frames after doing the animations.

It's going to be a bit tedious.